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Alva is a class M planet, the second planet in the Edison star system. It was named after the famous American scientist, Thomas Alva Edison.

Alva housed a Terran commercial colony, which was started by an investment group on Earth sometime between the 2220s and 2230s.

In the late 2260s, Pat Bradley, Montgomery Scott, Leonard McCoy, and Spock of the USS Enterprise beamed down to do a routine check on the colony for medical supplies and technology. The away team was ambushed by a squad of Klingons, led by King Klandor. Klandor planned a takeover by beaming aboard the Enterprise with Spock.

The invasion was thwarted, however, due to the intervention of an "angel", who held Spock and Klandor in limbo in another dimension. The angel turned out to be a small, childish shapeshifting creature who only wanted the two as a means of entertainment. Once they were returned to normal space, Spock was able to recover before the Klingon boarding party and rendered them unconscious with a Vulcan nerve pinch. The Klingons were then placed in a prison on the planet's surface. (TOS - Star Trek III Short Stories short story: "A Vulcan, A Klingon, and an Angel")

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planets visited by the USS Enterprise (NCC-1701) during Captain Kirk's initial five-year mission (2265-2270)
various Aprilia IIICaporyGarrusTriangularis III
2265 EarthDraxis IITallyGamma Alpha VPollux IIStarbase 8 planetSector Vega 6 planetM-155Archernar IVDimorusTendar IVMestikoAlpha Ortelina VIIArronus VIIAldebaran IIIDelta Vega IStarbase 12VelluriusEarthEmpyreaGlobular planetNorusJunkyard planetPalnak's planetSantarNova XIIIZeltokKorakTraveler's homeworldDukarNeesanAlgenib II
2266 Crucial-3VultraRobots' planetAngomaMantis planetNuofoStaiVrexBalant planetZargotColtacRigel XIIAlfa 177M-113Psi 2000Tlaoli IVSkurSelkyeTaragonAlpha 332Ynobe IIEcnalRayloNorigaAlpha Proxima IIArgylusOminnusEarthK-GSeggorForniaAngiraBeta IINeesanKujalLunaBwujaFayoHerculaEarthKibo/NdoraNrakaAlpha 23-COordonMobitaJodarrQuodarZartaFloe IMetamorphaInicrustMortiTerrellian IIVoodoo planetRiza homeworldMila XaKrugar III remnantQuaraxusArimaMazdaNumero UnoBeta CarinaeExo III1324-IV7348-IITantalus VMiri's homeworldPlanet QBenecia
2267 Taurus IIMakus IIIXimega IIHydra Epsilon IIIPerseus Arm planetoidYkoTenkaraSalvumGrotusVaranu planetYkoTalos IVTektonRifas-LAmusement Park planetHeitius VIICentaurus VFomalhaut VTyrtaeus IIGothosBeta VITheta VIIRamedes IIICestus IIIAlvaLazarus's planetZutotanium planetoidCygnet XIVEarthCanaraBeta IIIDraqqanaEminiar VIICeti Alpha VGamma 400VartaxDak-AlphaTimshelOmicron Ceti IIIJanus VI7348-IIChandra IVOrganiaAngrenaYkoEarth Colony IIGatewayEarthVandros VIIDeneva • "the Frontier" • ModalaGamma XaridianElsinor H-25Starbase 10Beta Mariotia IIIVega IIITondusVarkan asteroidTekkorCarnakCertaxPyris VIIEarthPentam VGamma Canaris NNukoleeStyraLurotaGiant Brain asteroidOtari IIGatewayIsis IIIMaaba S'JaCapella IVPollux IVVulcanMestikoNadorTactis IIBeta Nirobi IIPhygma IVOutpost Omega-70Tau Gamma IVM-370Argelius IIMerope IVMalurEulusDonico IIGamma Trianguli VIMasabaLekythosTyrtaeus IIShroud IVHalkaIxtoldeGamma Hydra IVCalydonBelmara IVTuran Tot Narut's planetGamma Canaris NTaunusPlanet 656Beton IIIKwettirJanvarZettinSklurrKarrGraktanTharkMorkolPlixesAndriusMuddEarthAneher IIWezonvuNalaingMagna RomaBavaryaNeolithiaMythraRimilliaBabelGamma Canaris NVulcanNisusNarnel's WorldNeuralBeta Canzadia III
2268 Fornax IIGamma IITriskelionArgus XTycho IVCentaurusUsildeTheta VIISigni BetaTautee systemBeta Canzandia IIIMevinnaSigma Iotia IIXanviaXoxxaInquisitor's planetBeta ReticuliDelta VegaNalogenDelta VegaDelta Canaris IVAlnath IIAmmdonArretEkosEeiauoSivaoKahlessOmega IVEarthTheta Kiokis IIElasTroyiusTau Delta IXAmerindTranquility VIIMinos VEarthExo IIIT'nufoTortugaTaos IVTriacusMarcos XIILowariaDreamers' planetSigma Draconis VIDireidiMedusaElcidar Beta IIIMinara IIOctavius IVBeta CabriniPegasus IVCareta VBeta XII-APlatoniusIzellEarthScalos M-317Beta Aurigae IIISanoora host planetRhinegeltKalandan outpostBrellian IVPrastorDistrelTttnicktttnorAriannusCheronElba IISanctuaryGideonKolya
2269 Memory AlphaMerak IIArdanaPollux VAvalonBalkos IIINova Atar IIIVesbiusJanus VIPollux IILeora IVWaasertlaMygdalus IIICentaurusRaga's PlanetEdenTheta Tau VHolberg 917GBeta Niobe IIIExcalbiaSarpeidonCamus IIDuwamishEphrata IVSigma Niobe IIGatewayKrasniMaltos IVOrganiaKyrosBeta CastelliNestaAnomalyAcademyArachnaeLyraBabelEpsilon Delta IVHeartlandMemory PrimeTalin IVSyhaar PrimeGatewayMantillesTaurus IIBeta Omicron Delta IIIMotherlodeMegas-TuTerratinSherman's PlanetThe StrandAarak IIIPhi XIUr homeworldVidenDengella IIEphrata IVGobi IIIPacificaGralafiLoren VArgoWaycrossPerryDelta Gamma IVDetente ITrefolgTrellisaneBeta CastelliHeloxBoaco VIJuram VVancadiaChyrellkaVeletus VPatria IPelos
2270 Janus VIPhylos IIVedala asteroidDramiaDramia IIArretLactra VIIBoqu IINGC 7332Delta Theta IIIPandroBriamosBelarius IVVelat Nol/R-836 IIN'caiStellaLiticiaGelladorn/R-775 ICenotaphVehtora IVMuldoonTaygeta VOkeanosBeta Omicron Delta IIIYoondriGatewayZeta GibraltarAndrosYusubEarth (alternate)SycoraxBira IIINjuraOmne's planetVoranRazarMercanAleriadAritaniYalboVulcanUnnamed Hoshan planetsTanisAragosAleph PrimeAleph IIIAntos IVTakoi homeworldEarthDenebiaVeneu IIKlondike VIIsitra ZeroPelosArchernar IVTalos IVPillagra/R-855EarthStarbase 12Tomarii

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