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Centurius III was a planet, the third planet in the Centurius star system on the edge of the Romulan Neutral Zone, somewhere in the space of the galaxy's Alpha or Beta Quadrants.
In around 2170, during the First Romulan-Federation War, it was destroyed. By a hundred years later, it was still considered uninhabitable due to radiation levels. (TOS video game: 25th Anniversary)